Development of the “Diverted Heck” Reaction for the Synthesis of Five-Membered Rings
نویسندگان
چکیده
The “diverted Heck” reaction has been shown to be a potent method synthesize cyclopropanes from electron-rich olefins and iodomethyl trifluoroborate. Nevertheless, it is not mechanistically limited the three-membered rings. synthesis of five-membered rings using bifunctional substrates with halide moiety an organometallic group described. Furthermore, reactions respective boron tin-based are further investigated optimized.
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ژورنال
عنوان ژورنال: Organometallics
سال: 2021
ISSN: ['1520-6041', '0276-7333']
DOI: https://doi.org/10.1021/acs.organomet.1c00025